Matthew 6:33
But seek ye first the kingdom of God, and his righteousness; and all these 
things shall be added unto you.
KJV
 
What is God's kingdom? John and Jesus both said at the 
start of their ministries that it was "at hand" (Matt. 3:2; 4:17). Jesus said 
that some in his generation would see the kingdom come (Mark 9:1). Daniel 
prophesied that the kingdom would come in the days of the Roman empire (Daniel 
2:44). After Pentecost, Paul wrote that the members of the Colosse church had 
been translated into God's Son's kingdom (Colossians 1:13), and John wrote to 
the seven churches that Christ had made them a kingdom (Rev. 1:6) and that he 
was their brother and companion in the kingdom (Revelation 1:9). Therefore, the 
kingdom must be the church.
What is the church? The Greek is "ekklesia," which literally means an assembly. 
In the religious context, it means the universal assembly (Matthew 16:18) or the 
local assembly (Romans 16:16) of Christians.
So if the assembly (church - universal and/or local) is the kingdom of 
God...then what are we to seek first, i.e., make our top priority (Matthew 
6:33)? The church, the assembly.
With that in mind, if the church meets for worship on a Sunday night, or Bible 
study on a Sunday morning or Wednesday night, or for a meal on Sunday afternoon, 
or a "work day" on Saturday afternoon, then if you could be there and yet choose 
not to be...are you truly "seeking first God's kingdom"? Of course not.
If the elders have decided that a congregation meets for Bible study twice a week and worship twice in a day, then seeking God's righteousness first would mean that one would obey Hebrews 13:17 and attend those assemblies. If one is in a congregation without elders, then seeking God's kingdom first would mean that one would do one's best to be there whenever the doors are open.
Harmonize this verse with Hebrews 10:25